IndiumV3, Chine, Analysis, bibRecord, 001551

Soluble axially substituted phthalocyanines : Synthesis and nonlinear optical response

Identifieur interne : 001551 ( Chine/Analysis ); précédent : 001550; suivant : 001552

Soluble axially substituted phthalocyanines : Synthesis and nonlinear optical response

Auteurs : RBID : Pascal:06-0262679

Descripteurs français

Pascal (Inist)
- Article synthèse, Préparation chimique, Synthèse chimique, Phtalocyanine métallique, Indium complexe, Titane complexe, Gallium complexe, Coordinat organique, Phtalocyanine, Propriété optique, Propriété non linéaire, Propriété électronique, 4270N.

English descriptors

KwdEn :
- Chemical preparation, Chemical synthesis, Electronic properties, Gallium complex, Indium complex, Metallophthalocyanine, Non linear properties, Optical properties, Organic ligand, Phthalocyanine, Review, Titanium complex.

Abstract

This review lays special stress on describing the synthesis of soluble axially substituted or bridged indium, gallium and titanium phthalocyanine complexes and their electronic absorption characteristics, photophysical and nonlinear optical properties. The enhanced solubility of the axially substituted or bridged phthalocyanine monomers and dimers, compared to the chloro analogues, shows that the usual tendency of phthalocyanines to form aggregates can be effectively suppressed by axial substitution. Axial substitution in phthalocyanine complexes has provoked relevant changes on the electronic structure of the molecule by altering the π-electronic distribution due to the dipole moment of the central metal-axial ligand bond. The nanosecond nonlinear absorption and the optical limiting of indium, gallium and titanium phthalocyanines seem to be dominated by a strong triplet state absorption in the optical region comprised between the Q- and B-bands in their UV/Vis absorption spectra.

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Pascal:06-0262679

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Soluble axially substituted phthalocyanines : Synthesis and nonlinear optical response</title>
<author><name>YU CHEN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Lab for Advanced Materials, East China University of Science and Technology, 130 Meilong Road</s1>
<s2>Shanghai 200237</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Shanghai 200237</wicri:noRegion>
</affiliation>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut ftir Organische Chemie, Organische Chemie II, Universität Tübingen, Auf der Morgenstelle 18</s1>
<s2>72076 Tübingen</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
</inist:fA14>
<country>Allemagne</country>
<placeName><region type="land" nuts="1">Bade-Wurtemberg</region>
<region type="district" nuts="2">District de Tübingen</region>
<settlement type="city">Tübingen</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Hanack, Michael" uniqKey="Hanack M">Michael Hanack</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Institut ftir Organische Chemie, Organische Chemie II, Universität Tübingen, Auf der Morgenstelle 18</s1>
<s2>72076 Tübingen</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<country>Allemagne</country>
<placeName><region type="land" nuts="1">Bade-Wurtemberg</region>
<region type="district" nuts="2">District de Tübingen</region>
<settlement type="city">Tübingen</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Blau, Werner J" uniqKey="Blau W">Werner J. Blau</name>
<affiliation wicri:level="1"><inist:fA14 i1="03"><s1>Materials Ireland Polymer Research Centre, Department of Physics, Trinity College Dublin</s1>
<s2>Dublin</s2>
<s3>IRL</s3>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Irlande (pays)</country>
<wicri:noRegion>Dublin</wicri:noRegion>
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</author>
<author><name sortKey="Dini, Danilo" uniqKey="Dini D">Danilo Dini</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Lab for Advanced Materials, East China University of Science and Technology, 130 Meilong Road</s1>
<s2>Shanghai 200237</s2>
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<country>République populaire de Chine</country>
<wicri:noRegion>Shanghai 200237</wicri:noRegion>
</affiliation>
</author>
<author><name>YING LIU</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Lab for Advanced Materials, East China University of Science and Technology, 130 Meilong Road</s1>
<s2>Shanghai 200237</s2>
<s3>CHN</s3>
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<country>République populaire de Chine</country>
<wicri:noRegion>Shanghai 200237</wicri:noRegion>
</affiliation>
</author>
<author><name>YING LIN</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Lab for Advanced Materials, East China University of Science and Technology, 130 Meilong Road</s1>
<s2>Shanghai 200237</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
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</inist:fA14>
<country>République populaire de Chine</country>
<wicri:noRegion>Shanghai 200237</wicri:noRegion>
</affiliation>
</author>
<author><name>JINRUI BAI</name>
<affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Lab for Advanced Materials, East China University of Science and Technology, 130 Meilong Road</s1>
<s2>Shanghai 200237</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
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<country>République populaire de Chine</country>
<wicri:noRegion>Shanghai 200237</wicri:noRegion>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="inist">06-0262679</idno>
<date when="2006">2006</date>
<idno type="stanalyst">PASCAL 06-0262679 INIST</idno>
<idno type="RBID">Pascal:06-0262679</idno>
<idno type="wicri:Area/Main/Corpus">008F77</idno>
<idno type="wicri:Area/Main/Repository">008401</idno>
<idno type="wicri:Area/Chine/Extraction">001551</idno>
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<seriesStmt><idno type="ISSN">0022-2461</idno>
<title level="j" type="abbreviated">J. mater. sci.</title>
<title level="j" type="main">Journal of materials science</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Chemical preparation</term>
<term>Chemical synthesis</term>
<term>Electronic properties</term>
<term>Gallium complex</term>
<term>Indium complex</term>
<term>Metallophthalocyanine</term>
<term>Non linear properties</term>
<term>Optical properties</term>
<term>Organic ligand</term>
<term>Phthalocyanine</term>
<term>Review</term>
<term>Titanium complex</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Article synthèse</term>
<term>Préparation chimique</term>
<term>Synthèse chimique</term>
<term>Phtalocyanine métallique</term>
<term>Indium complexe</term>
<term>Titane complexe</term>
<term>Gallium complexe</term>
<term>Coordinat organique</term>
<term>Phtalocyanine</term>
<term>Propriété optique</term>
<term>Propriété non linéaire</term>
<term>Propriété électronique</term>
<term>4270N</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">This review lays special stress on describing the synthesis of soluble axially substituted or bridged indium, gallium and titanium phthalocyanine complexes and their electronic absorption characteristics, photophysical and nonlinear optical properties. The enhanced solubility of the axially substituted or bridged phthalocyanine monomers and dimers, compared to the chloro analogues, shows that the usual tendency of phthalocyanines to form aggregates can be effectively suppressed by axial substitution. Axial substitution in phthalocyanine complexes has provoked relevant changes on the electronic structure of the molecule by altering the π-electronic distribution due to the dipole moment of the central metal-axial ligand bond. The nanosecond nonlinear absorption and the optical limiting of indium, gallium and titanium phthalocyanines seem to be dominated by a strong triplet state absorption in the optical region comprised between the Q- and B-bands in their UV/Vis absorption spectra.</div>
</front>
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<fA03 i2="1"><s0>J. mater. sci.</s0>
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<fA06><s2>8</s2>
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<fA08 i1="01" i2="1" l="ENG"><s1>Soluble axially substituted phthalocyanines : Synthesis and nonlinear optical response</s1>
</fA08>
<fA11 i1="01" i2="1"><s1>YU CHEN</s1>
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<fA11 i1="02" i2="1"><s1>HANACK (Michael)</s1>
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<fA11 i1="05" i2="1"><s1>YING LIU</s1>
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<fA11 i1="06" i2="1"><s1>YING LIN</s1>
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<fA11 i1="07" i2="1"><s1>JINRUI BAI</s1>
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<fA14 i1="01"><s1>Department of Chemistry, Lab for Advanced Materials, East China University of Science and Technology, 130 Meilong Road</s1>
<s2>Shanghai 200237</s2>
<s3>CHN</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
<sZ>5 aut.</sZ>
<sZ>6 aut.</sZ>
<sZ>7 aut.</sZ>
</fA14>
<fA14 i1="02"><s1>Institut ftir Organische Chemie, Organische Chemie II, Universität Tübingen, Auf der Morgenstelle 18</s1>
<s2>72076 Tübingen</s2>
<s3>DEU</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<fA14 i1="03"><s1>Materials Ireland Polymer Research Centre, Department of Physics, Trinity College Dublin</s1>
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<fC01 i1="01" l="ENG"><s0>This review lays special stress on describing the synthesis of soluble axially substituted or bridged indium, gallium and titanium phthalocyanine complexes and their electronic absorption characteristics, photophysical and nonlinear optical properties. The enhanced solubility of the axially substituted or bridged phthalocyanine monomers and dimers, compared to the chloro analogues, shows that the usual tendency of phthalocyanines to form aggregates can be effectively suppressed by axial substitution. Axial substitution in phthalocyanine complexes has provoked relevant changes on the electronic structure of the molecule by altering the π-electronic distribution due to the dipole moment of the central metal-axial ligand bond. The nanosecond nonlinear absorption and the optical limiting of indium, gallium and titanium phthalocyanines seem to be dominated by a strong triplet state absorption in the optical region comprised between the Q- and B-bands in their UV/Vis absorption spectra.</s0>
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<fC02 i1="02" i2="3"><s0>001B40B70N</s0>
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<fC03 i1="01" i2="X" l="FRE"><s0>Article synthèse</s0>
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<s5>01</s5>
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<s5>01</s5>
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<s5>02</s5>
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<s5>02</s5>
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<s5>03</s5>
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<s5>03</s5>
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<s5>03</s5>
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<fC03 i1="04" i2="X" l="FRE"><s0>Phtalocyanine métallique</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="X" l="ENG"><s0>Metallophthalocyanine</s0>
<s5>06</s5>
</fC03>
<fC03 i1="04" i2="X" l="SPA"><s0>Ftalocianina metálica</s0>
<s5>06</s5>
</fC03>
<fC03 i1="05" i2="X" l="FRE"><s0>Indium complexe</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="X" l="ENG"><s0>Indium complex</s0>
<s5>07</s5>
</fC03>
<fC03 i1="05" i2="X" l="SPA"><s0>Indio complejo</s0>
<s5>07</s5>
</fC03>
<fC03 i1="06" i2="X" l="FRE"><s0>Titane complexe</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="X" l="ENG"><s0>Titanium complex</s0>
<s5>08</s5>
</fC03>
<fC03 i1="06" i2="X" l="SPA"><s0>Titanio complejo</s0>
<s5>08</s5>
</fC03>
<fC03 i1="07" i2="X" l="FRE"><s0>Gallium complexe</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="X" l="ENG"><s0>Gallium complex</s0>
<s5>09</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Galio complejo</s0>
<s5>09</s5>
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<fC03 i1="08" i2="X" l="FRE"><s0>Coordinat organique</s0>
<s5>10</s5>
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<fC03 i1="08" i2="X" l="ENG"><s0>Organic ligand</s0>
<s5>10</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Ligando orgánico</s0>
<s5>10</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Phtalocyanine</s0>
<s2>FC</s2>
<s2>NK</s2>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Phthalocyanine</s0>
<s2>FC</s2>
<s2>NK</s2>
<s5>11</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Ftalocianina</s0>
<s2>FC</s2>
<s2>NK</s2>
<s5>11</s5>
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<s5>12</s5>
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<s5>12</s5>
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<s5>13</s5>
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<fC03 i1="12" i2="X" l="FRE"><s0>Propriété électronique</s0>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Electronic properties</s0>
<s5>14</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Propiedad electrónica</s0>
<s5>14</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>4270N</s0>
<s2>PAC</s2>
<s4>INC</s4>
<s5>92</s5>
</fC03>
<fC07 i1="01" i2="X" l="FRE"><s0>Métal complexe</s0>
<s5>04</s5>
</fC07>
<fC07 i1="01" i2="X" l="ENG"><s0>Metal complex</s0>
<s5>04</s5>
</fC07>
<fC07 i1="01" i2="X" l="SPA"><s0>Metal complejo</s0>
<s5>04</s5>
</fC07>
<fC07 i1="02" i2="3" l="FRE"><s0>Métal transition complexe</s0>
<s5>05</s5>
</fC07>
<fC07 i1="02" i2="3" l="ENG"><s0>Transition element complexes</s0>
<s5>05</s5>
</fC07>
<fN21><s1>170</s1>
</fN21>
</pA>
</standard>
</inist>
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Soluble axially substituted phthalocyanines : Synthesis and nonlinear optical response

Soluble axially substituted phthalocyanines : Synthesis and nonlinear optical response

Descripteurs français

English descriptors

Abstract

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Links to Exploration step

Le document en format XML

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